Illustrated Glossary of Organic Chemistry
Uni
molecular
:
A reaction,
mechanism step
, or other process involving only one
molecule
.
Ionization
of a carbon-
leaving group
bond
, the
rate-determining step
of an
S
N
1 reaction
, is uni
molecular
. Its
rate equation
is
rate
= k [(H
3
C)
3
CBr].
The
rate-determining step
of an
S
N
2 reaction
is
bimolecular
. Its
rate equation
is
rate
= k [CH
3
Br] [
HO
-
].
A
termolecular
mechanism step
is nearly impossible due to the very low probability of simultaneous collision of three
reactants
. The
termolecular
substitution reaction
mechanism
shown here does not occur. The actual
mechanism
(
S
N
1
) involves three steps.
Related terms:
Trimolecular
,
E2 mechanism
,
E1 mechanism
,
concerted reaction
,
rate law
,
rate expression
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