Illustrated Glossary of Organic Chemistry

Stoichiometry: The study of the relationship between quantity of reactants and products in a chemical reaction.

In this SN2 reaction, one mole of CH3Cl (molar mass = 50.49 g mol-1) reacts with one mole of NaI (molar mass =  149.89 g mol-1) to produce one mole of CH3I (molar mass = 141.95 g mol-1) plus one mole of NaCl (molar mass = 58.44 g mol-1). From this we can deduce that 29.7 g of NaI (0.198 mole) are required to completely react with 10.0 g (0.198 mole) of CH3Cl and that this reaction will produce 28.1 g (0.198 mole) of CH3I and 11.6 g (0.198 mole) of NaCl.

In this catalytic hydrogenation reaction, one mole of acetylene (molar mass = 26.04 g mol-1) reacts with two moles of H2 (molar mass = 2.016 g mol-1) and a catalytic amount of Pt to produce one mole of ethane (molar mass = 30.07 g mol-1). From this we can deduce that 20.0 liters of H2 gas (1.800 g; 0.893 mole under standard conditions) are required to completely react with 10.0 liters of acetylene (11.6 g; 0.446 mole under standard conditions), and that this reaction will produce 10.0 liters of ethane (13.4 g; 0.446 mole under standard conditions). Pt is the catalyst and therefore not consumed in the reaction. The amount of Pt present controls the reaction rate, but not the reaction stoichiometry.