Illustrated Glossary of Organic Chemistry - Mutarotation

Illustrated Glossary of Organic Chemistry

Mutarotation: The change in optical activity as a monosaccharide reaches equilibrium between its α and β-anomers.


α-D-glucopyranose		Equilibrium mixture		β-D-glucopyranose
[α] = +112.2^o		[α] = +52.5^o		[α] = +18.7^o
		36% α and 64% β

Related terms: Carbohydrate, pyranose, optically active, optically inactive, specific rotation, polarimetry, polarimeter, anomeric carbon, stereocenter, arrows
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