Illustrated Glossary of Organic Chemistry

m/z (mass-to-charge ratio): In mass spectrometry the ratio of an ion's mass (m) in atomic mass units (amu) to its formal charge (z). Formal charge is usually +1. The units for m/z are usually not included.


Fragmentation

CH3CH2CH2+
 +

Molecular ion

Fragments
Formula = C5H12O
Mass = 88 amu
Charge = +1
m/z = 88

Formula = C3H7
Mass = 43 amu
Charge = +1
m/z = 43

Formula = C2H5O
Mass = 45 amu
Charge = +1
m/z = 45